CALCIUM CITRATE
|
PRODUCT
IDENTIFICATION
|
CAS
NO. |
813-94-5 |
|
EINECS NO. |
212-391-7 |
FORMULA |
Ca3(C6H5O7)2·4H2O |
MOL
WT. |
570.50 |
H.S.
CODE
|
2918.15 |
SMILES
|
|
CLASSIFICATION
|
|
TOXICITY
|
very
low |
SYNONYMS |
Citric acid calcium salt; Tricalcium citrate; |
2-Hydroxy-1,2,3-Propanetricarboxylic acid,
calcium salt (2:3); Tricalcium dicitrate;
Citrical;
柠檬酸钙
(Chinese); Calciumcitraat (Dutch);
Citrate De Calcium (French); Kalziumzitrat
( German); Citrato Del Calcio (Italian);
Citrato Do
Calcio (Portuguese); Citrato Del Calcio (Spanish); |
PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
White
crystalline powder |
MELTING POINT |
|
BOILING
POINT |
|
SPECIFIC GRAVITY |
|
SOLUBILITY
IN WATER |
almost insoluble |
pH |
5.6
- 5.8 (5% sol.) |
VAPOR DENSITY |
practically
0 |
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health: 1; Flammability: 0; Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable
under ordinary conditions |
APPLICATIONS
|
Commonly called
Calcium Citrate is chemically Tricalcium
Dicitrate Tetrahydrate, the most commonly used calcium salt of citric acid. It
is a white, odourless powder, generally permitted as a safe nutrient and food additive
having functions of acidity regulator, sequestering and stabilizing agent ,
antioxidants synergist, firming agent, Calcium enrichment in foods and medicine. It
is physiologically completely compatible like citric acid.
|
SALES
SPECIFICATION |
BIBLIOGRAPHY
|
FCC
IV
|
APPEARANCE
|
White
fine powder or granular |
ASSAY |
97.5 - 100.5% |
CALCIUM CONTENT |
23.5-24.2% (Anhydrous Basis
), 20.5-21.2%(Tetrahydrate Basis ) |
ORGANIC VOLATILES |
Complies
|
LOSS ON DRYING |
10.0 - 13.3% |
HEAVY METALS |
0.002%
max |
ACID INSOLUBLES |
0.2%
max |
FLUORIDE |
0.003%
max |
LEAD (as Pb) |
0.001%
max |
ARSENIC (as As) |
0.0003%
max |
PARTICLE
SIZE |
90%
min ( 80mesh ) : powder 80% min (20 -
60mesh) granule |
TRANSPORTATION |
PACKING |
25kgs
in Bag,
20mts in Container |
HAZARD CLASS |
Not
regulated |
UN
NO. |
|
GENERAL
DESCRIPTION OF CITRIC ACID
|
Citric Acid (2-Hydroxy-1,2,3-propanetricarboxylic acid, in IUPAC naming) is a
colourless crystalline organic compound belong to carboxylic acid family. It
exists in all plants (especially in lemons and limes) and in many animal tissues
and fluids. In biochemistry, it is involved in important metabolism of almost
all living things; the Krebs cycle (also called citric acid cycle or
tricarboxylic acid cycle), a part of the process by which animals convert food
to energy. Citric acid works as a preservative ( or as an antioxidant) and
cleaning agent in nature. It is commercially obtained by fermentation process of
glucose with the aid of the mold Aspergillus niger and can be obtained
synthetically from acetone or glycerol. It can be used as an sour taste enhancer
in foods and soft drinks. The three carboxy groups lose protons in solution;
resulting in the excellent pH control as a buffer in acidic solutions. It is
used as a flavouring, stabilizing agent and acidulant (to control acidity) in
food industry, in metal-cleaning compositions as it chelates metals. Citric acid
is available in forms of anhydrous primarily and in monohydrate, the
crystallized form from water. The hydrated form will be converted to the
anhydrous form above 74 C. Citrate is a salt or ester of citric acid. Citrates
are formed by replacing the acidic one, two, or all three of the carboxylic
hydrogens in citric acid by metals or organic radicals to produce an extensive
series of salts, esters, and mixed (double) salts. Cirrates are used in food,
cosmetics, pharmaceutical and medicine industries as well as in plastic
industry; nutrient or food additives having functions of acidity regulator,
sequestering and stabilizing agent, antioxidants synergist, firming agent;
anticoagulant for stored whole blood and red cells and also for blood specimens
as citrates chelate metal ions and saline cathartics, effervescent medicines;
high boiling solvent, plasticizer and resin for food contact plastics.
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